It’s late, and my thermodynamics is more than a little rusty, however I think it goes like this Rick ....
The bulk chemical absorbs energy to enable the change of state as it evaporates. It will cool the surroundings by doing this. As it thermally re-equilibrates to the surroundings the bulk will reduce in temperature, so reducing the rate of evaporation. The only bit that can actually increase in temperature is the released gaseous phase.......unless the bulk is in a closed vessel and is able to increase in temperature without changing state because it increases pressure instead.....the gas laws are in there somewhere.....
You can test this by the sacrilegious spilling of good alcohol on your skin, you can feel your skin cool as it evaporates....
Jakko, if the catalyst is liquid it will be consumed in the reaction, so will not be a catalyst, just an accelerant, so liquefying it will nullify it’s catalytic qualities.....
Long time since I did chemistry, so I may be way off beam.....I did get a first though, so hope I haven’t forgotten too much LOL....